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Carbonyl compounds and dissolved organic carbon in rainwater of an urban atmosphere.

TitleCarbonyl compounds and dissolved organic carbon in rainwater of an urban atmosphere.
Publication TypeJournal Article
Year of Publication2014
AuthorsBalla, D., Papageorgiou A., & Voutsa D.
JournalEnviron Sci Pollut Res Int
Volume21
Issue20
Pagination12062-73
Date Published2014 Oct
ISSN1614-7499
KeywordsAldehydes, Atmosphere, Carbon, Cities, Gases, Geography, Greece, Organic Chemicals, Rain, Solubility, Spectrometry, Fluorescence, Spectrophotometry, Ultraviolet, Statistics, Nonparametric, Water Pollutants, Chemical
Abstract

This study investigates the occurrence of carbonyl compounds in rainwater at the city of Thessaloniki, Northern Greece. The concentrations of carbonyl compounds (as sum of 14 compounds) ranged from 21.8 to 592 μg/L, mean concentration 119 μg/L. Formaldehyde, acetaldehyde, hexanal, glyoxal, and methylglyoxal were the dominant compounds. DOC concentrations in rainwater ranged from 0.46 to 21.3 mg/L. UV-Vis and fluorescence spectra characteristics showed variation among rain events. Carbonyl compounds were negatively correlated with temperature exhibited relatively higher concentrations in cold season. They also influenced by storm origin with higher concentrations under terrestrial air masses. Calm conditions enhance the concentrations of DOC. Wash out is an effective removal mechanism of DOC.

DOI10.1007/s11356-014-3080-8
Alternate JournalEnviron Sci Pollut Res Int
PubMed ID24920258

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